Beilstein J. Org. Chem.2019,15, 2161–2169, doi:10.3762/bjoc.15.213
electron-withdrawing cyano groups than when they are electron-donating methoxy groups.
Keywords: aromatic stabilization energy; diarylethene; ruthenium(I) catalysedHuisgencyclization; terarylene; thermally reversible photochromism; Introduction
Diarylethenes are one of the most widely investigated
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Graphical Abstract
Scheme 1:
Reaction mechanisms of Huisgen cyclization catalyzed by Cu(I) and Ru(I).